ASTM E1508 PDF
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These values are given in Table 5. Most sources of bias asmt either insigni? Longer counting times and increased beam current produce more counts.
Each participant was requested to analyze?
ASTM E1508 – 12a
EDS detectors do not resolve all peaks. Although results of the standardless analyses were rather good on the Type stainless steel, they may be considerably inferior on other types of specimens.
It may be that differences in background subtraction, peak deconvolution method, matrix correction, and possibly geometric con? Additional items that may be reported include what standards were used, if any, the beam current, and the Z, A, and F factors.
Astmm comments will receive careful consideration at a meeting of the responsible technical committee, which you may attend. Software is usually available to calibrate the Ashm system, and one should consult the system manual for the r1508 of operation. Windowless detectors approach the theoretical highest efficiency of the detecting crystal, but in the open position contaminants in the sample chamber are free to condense on the cold crystal.
If the voltage measured in this manner is much lower than the voltage setting, it may be an indication that the specimen is charging. The two elements need not be in the satm specimen.
ASTM E – 12a – Standard Guide for Quantitative Analysis by Energy-Dispersive Spectroscopy
It does not affect spatial resolution for X-ray analysis in the same way it detracts from electron image resolution. If standards are used, they must be collected under the identical geometrical conditions as the unknowns. All distances must be in the same units. A superscript epsilon e indicates an editorial change since the last revision or reapproval.
Consequently, one would expect the most improvement using a phi-rho-z method in light element analysis. Evaporated carbon is usually the most suitable coating material. The artifact cannot occur at energies below the absorption edge of the Si K line, and it becomes negligible at higher energies such as the Cu Ka line. The coatings are usually applied in thicknesses of several tens of nanometres.
The nominal composition of each specimen was also included for reference. The unknowns and standards must have been collected 1 under the same geometrical con?
An overvoltage of at least 1. For materials such as minerals and ceramics, which contain light elements that is, of low atomic number15 kV is usually a good compromise. The report should also specify whether standards or standardless methods were used, what matrix corrections were applied, and whether any elemental concentrations were calculated by difference or by stoichiometry. It would also be informative to mention the type of window on the EDS detector, if other than a conventional beryllium window.
Additionally, in the windowless mode any light, such as from cathodoluminescence, can be picked up by the crystal and will contribute to the overall noise of the system. The take-off angle is wstm Vertical distance is the distance from the bottom of the pole piece of the?
The number ast X-ray photons that reach the detector is a function of the solid angle and take-off angle, including the effect of specimen and detector tilt. This is often accomplished by painting a stripe of carbon or silver paint from the specimen to the specimen holder. If one is analyzing carbon in the specimen, then aluminum makes a good coating. The compositions of both alloys, as determined by wet chemical analysis, are given in Table 2.
A total of nine laboratories participated in the study. Referenced Documents purchase separately The documents listed below are referenced within the subject standard but are not provided as part of the standard. For the Type stainless steel, the average error was 0. Accordingly, most operators choose a 0—10 keV display at higher display resolution rather than a 0—20 keV display at lower resolution. Whichever method is used, all elements present must be speci? Light Element Analysis The alloy contained both high and low atomic number elements necessitating the use of K, L, and M lines.
Tables of X-ray energies can be found in various texts, such as Goldstein, et al2 or Johnson and White. The EDS values are the average of?
ASTM E – 12a Standard Guide for Quantitative Analysis by Energy-Dispersive Spectroscopy
The alloy MA specimen was selected because of its inherent homogeneity and because it presented several analytical problems. However, most matrix correction programs are sufficiently accurate to permit the use of pure element standards.
Spectrometer distance is the horizontal distance from the spectrometer to the beam; it is measured using the scale provided by the manufacturer on the spectrometer slide. Individual reprints single or multiple copies of this standard may be obtained by contacting ASTM at the above address or at phoneasgmor service r1508. The s count speci? Pileup peaks occur when several X-ray photons reach the detector at the same time, and the pulse processing e15008 erroneously record the sum of their energies rather than each one individually.
Sr SR r R Nickel 9. The presence of eight elements also added to the difficulty in analyzing this material. Originally approved in If the unknown and standard were identical, each of these factors would equal one.
Both specimens were analyzed by various metal producers, EDS system manufacturers, and one university. Defocusing the beam or scanning it over an area of varying composition does not provide an average composition, because the correction factors applied to the intensity ratio are themselves a function of composition.